Hair styling shampoos containing organic oil

ABSTRACT

Disclosed are hair shampoo compositions which provide cleaning and styling performance, and which contain latex polymer particles, water-soluble cationic polymer as a latex deposition aid, organic oil as a latex deposition aid, and typically one or more surfactants, an aqueous carrier and one or more optional ingredients. The organic oil is a hydrocarbon oil or fatty ester, and is present in an amount effective to enhance deposition of the latex polymer particles onto hair in the presence of cationic polymer.

CROSS REFERENCE TO RELATED APPLICATION

The instant application is a continuation application filed under 37C.F.R. §153(b) of U.S. Ser. No. 08/954,982 filed on Oct. 21, 1997 nowU.S. Pat. No. 6,113,890, which is a continuation of Ser. No. 08/522,873filed Sep. 1, 1995, now abandoned.

FIELD OF THE INVENTION

The present invention relates to hair shampoo compositions which providecleaning and styling benefits. These are achieved by incorporatingdispersed latex polymer particles, cationic polymer and organic oil intoshampoo compositions.

BACKGROUND OF THE INVENTION

Many hair shampoo compositions provide acceptable cleaning but providelittle or no styling benefits, e.g. body, hold, stiffness. To realizesuch benefits, separate cleaning and styling products are often used.

Recently, hair shampoo compositions have been developed which canprovide cleaning performance with some styling benefits, all from asingle product. Many of these products contain styling polymers in acompatible shampoo base. To prepare such products. styling polymers canbe dissolved in an organic solvent and then incorporated into theshampoo base. The organic solvent thereafter helps disperse the stylingpolymer in the shampoo composition, and also helps enhance deposition ofthe styling polymer onto hair. The use of these solvents, however, cansometimes contribute undesirable odors to the finished product orotherwise present formulation problems, e.g. compatibility with othermaterials in the shampoo composition.

To minimize the use of these organic solvents, latex polymers ratherthan dissolved polymers have been employed as a means of incorporatingstyling polymers into a shampoo base. Latex polymer systems are stabledispersions, typically colloidal dispersions, of water-insoluble polymerparticles in a continuous aqueous phase. As such, there is little or noorganic solvent to contribute undesirable odors or to otherwise presentincompatibilities with other materials in the shampoo composition.Without the organic solvent, however, deposition of the latex particlesonto hair, which is essential for allowing the styling polymer to setand form a film onto the surface of hair, is reduced. Attempts atimproving latex deposition included adding latex deposition aids, e.g.,cationic polymers, and/or by increasing the shampoo concentration of thelatex polymer.

The foregoing considerations involving styling shampoo compositions andlatex polymer systems indicates that there is a continuing need toidentify latex polymer shampoos with enhanced latex deposition profilesand styling performance. Accordingly, it is an object of the presentinvention to provide such compositions, and further to provide suchcompositions that require minimal or reduced levels of latex polymer toachieve the desired latex deposition profile and styling performance.

SUMMARY OF THE INVENTION

The present invention is directed to hair shampoo compositions whichprovide cleaning and styling benefits. Compositions of this typecomprise dispersed latex polymer particles, cationic polymer and organicoil, wherein the organic oil is present in an amount effective toenhance deposition of the latex particles onto hair. The shampoocompositions will generally be in the form of pourable liquids underambient conditions and contain one or more compatible surfactants, anaqueous carrier, and one or more other optional materials.

DETAILED DESCRIPTION OF THE INVENTION

“Soluble” and “insoluble” used in reference to particular ingredients ofthe shampoo compositions refer to solubility or insolubility,respectively, of that ingredient in the shampoo composition of thepresent invention, unless otherwise specifically indicated. For examplethe terms “water soluble” and “water insoluble”, as used herein, referto solubility of the particular ingredient in water, as opposed tosolubility in the shampoo composition.

All percentages, parts and ratios are based on weight unless otherwisespecified.

“Water soluble” refers to any material that is sufficiently soluble inwater (distilled or equivalent) at 25° C. to form a substantially clearsolution containing at least about 0.1% by weight of the material.

“Water insoluble” refers to any material that is not water soluble asdefined herein.

“Ambient conditions” refer to air temperatures of about 25° C. underabout 1 atm of pressure.

“Comprising” means various components can be conjointly employed in theshampoo compositions of the present invention. “Consisting essentiallyof” and “consisting of” are embodied in the term “comprising.”

Surfactant

The shampoo compositions of the present invention typically contain oneor more synthetic surfactants, which surfactants are physically andchemically compatible with the essential components of the shampoocompositions, or do not otherwise unduly impair cleaning and/or stylingperformance.

Synthetic surfactants for use in the shampoo compositions can becategorized as anionic, nonionic, cationic, zwitterionic or amphoteric,and will generally be present at a level from about 0.5% to about 50%,more typically from about 4% to about 30%, more typically from about 5%to about 25%, by weight, of the shampoo composition. Total surfactantconcentrations in the shampoo compositions can vary depending on theshampoo base formulation, the selected surfactant, cosurfactants,product results desired and so forth.

Anionic surfactants for use in the shampoo compositions include alkyland alkyl ether sulfates. These materials have the respective formulaeROSO₃M and RO(C₂H₄O)_(x)SO₃M, wherein R is alkyl or alkenyl of fromabout 8 to about 24 carbon atoms, x is 1 to 10, and M is a water-solublecation such as ammonium, sodium, potassium and triethanolamine. Thealkyl ether sulfates are typically made as condensation products ofethylene oxide and monohydric alcohol's having from about 8 to about 24carbon atoms. Preferably, R has from about 10 to about 18 carbon atomsin both the alkyl and alkyl ether sulfates. The alcohol's can be derivedfrom fats, e.g., coconut oil or tallow, or can be synthetic. Laurylalcohol and straight chain alcohol's derived from coconut oil arepreferred herein. Such alcohol's are reacted with about 1 to about 10,preferably from about 2 to about 5, especially about 3, molarproportions of ethylene oxide and the resulting mixture of molecularspecies having, for example, an average of 3 moles of ethylene oxide permole of alcohol, is sulfated and neutralized.

Specific examples of alkyl ether sulfates which may be used in theshampoo compositions are sodium and ammonium salts of coconut alkyltriethylene glycol ether sulfate; tallow alkyl triethylene glycol ethersulfate, and tallow alkyl hexaoxyethylene sulfate. Highly preferredalkyl ether sulfates are those comprising a mixture of individualcompounds, said mixture having an average alkyl chain length of fromabout 10 to about 16 carbon atoms and an average degree of ethoxylationof from about I to about 4 moles of ethylene oxide.

Another class of anionic surfactants suitable for use in the shampoocompositions are the water-soluble salts of the organic, sulfuric acidreaction products of the general formula [R¹—SO₃—M] wherein R¹ is chosenfrom the group consisting of a straight or branched chain, saturatedaliphatic hydrocarbon radical having from about 8 to about 24,preferably about 10 to about 18, carbon atoms; and M is a cation.Important examples are the salts of an organic sulfuric acid reactionproduct of a hydrocarbon of the methane series, including iso-, neo-,ineso-, and n-paraffins, having about 8 to about 24 carbon atoms,preferably about 10 to about 18 carbon atoms and a sulfonating agent,e.g., SO₃, H₂SO₄, oleum, obtained according to known sulfonationmethods, including bleaching and hydrolysis. Preferred are alkali metaland ammonium sulfonated C₁₀₋₁₈ n-paraffins.

Additional examples of anionic surfactants suitable for use in theshampoo compositions are the reaction products of fatty acids esterifiedwith isethionic acid and neutralized with sodium hydroxide where, forexample, the fatty acids are derived from coconut oil; sodium orpotassium salts of fatty acid amides of methyl tauride in which thefatty acids, for example, are derived from coconut oil. Other suitableanionic surfactants of this variety are described in U.S. Pat. Nos.2,486,921, 2,486,922 and 2,396,278.

Still other suitable anionic surfactants are the succinamates, whichincludes disodium N-octadecylsulfosuccinamate; diammonium laurylsulfosuccinamate; tetrasodiumN-(1,2-dicarboxyethyl)-N-octadecylsulfosuccinamate; diamyl ester ofsodium sulfosuccinic acid; dihexyl ester of sodium sulfosuccinic acid;and dioctyl esters of sodium sulfosuccinic acid.

Other suitable anionic surfactants include olefin sulfonates havingabout 12 to about 24 carbon atoms. The term “olefin sulfonates” is usedherein to mean compounds which can be produced by the sulfonation ofa-olefins by means of uncomplexed sulfur trioxide, followed byneutralization of the acid reaction mixture in conditions such that anysulfones which have been formed in the reaction are hydrolyzed to givethe corresponding hydroxy-alkanesulfonates. The sulfur trioxide can beliquid or gaseous, and is usually, but not necessarily, diluted by inertdiluents, for example by liquid SO₂, chlorinated hydrocarbons, etc.,when used in the liquid form, or by air, nitrogen, gaseous SO₂, etc.,when used in the gaseous form.

The a-olefins from which the olefin sulfonates are derived aremono-olefins having about 12 to about 24 carbon atoms, preferably about14 to about 16 carbon atoms. Preferably, they are straight chainolefins.

In addition to the true alkene sulfonates and a proportion ofhydroxy-alkanesulfonates, the olefin sulfonates can contain minoramounts of other materials, such as alkene disulfonates depending uponthe reaction conditions, proportion of reactants, the nature of thestarting olefins and impurities in the olefin stock and side reactionsduring the sulfonation process.

Another class of anionic surfactants suitable for use in the shampoocompositions are the b-alkyloxy alkane sulfonates. These compounds havethe following formula:

where R₁ is a straight chain alkyl group having from about 6 to about 20carbon atoms, R₂ is a lower alkyl group having from about 1 (preferred)to about 3 carbon atoms, and M is a water-soluble cation as hereinbeforedescribed.

Other suitable surfactants are described in McCutcheon's Emulsifiers andDeterrents. 1989 Annual, published by M. C. Publishing Co., and in U.S.Pat. No. 3,929,678, which descriptions are incorporated herein byreference.

Preferred anionic surfactants for use in the shampoo compositionsinclude ammonium lauryl sulfate, ammonium laureth sulfate, triethylaminelauryl sulfate, triethylamine laureth sulfate, triethanolamine laurylsulfate, triethanolamine laureth sulfate, monoethanolamine laurylsulfate, monoethanolamine laureth sulfate, diethanolamine laurylsulfate, diethanolamine laureth sulfate, lauric monoglyceride sodiumsulfate, sodium lauryl sulfate, sodium laureth sulfate, potassium laurylsulfate, potassium laureth sulfate, sodium lauryl sarcosinate, sodiumlauroyl sarcosinate, lauryl sarcosine, cocoyl sarcosine, ammonium cocoylsulfate, ammonium lauroyl sulfate, sodium cocoyl sulfate, sodium lauroylsulfate, potassium cocoyl sulfate, potassium lauryl sulfate,triethanolamine lauryl sulfate, triethanolamine lauryl sulfate,monoethanolamine cocoyl sulfate, monoethanolamine lauryl sulfate, sodiumtridecyl benzene sulfonate, and sodium dodecyl benzene sulfonate.

Amphoteric surfactants suitable for use in the shampoo compositions canbe broadly described as derivatives of aliphatic secondary and tertiaryamines in which the aliphatic radical can be straight or branched chainand wherein one of the aliphatic substituents contains from about 8 toabout 18 carbon atoms and one contains an anionic water solubilizinggroup, e.g., carboxy, sulfonate, sulfate, phosphate, or phosphonate.Examples of compounds falling within this definition are sodium3-dodecylaminopropionate, sodium 3-dodecylaminopropane sulfonate, sodiumlauryl sarcosinate, N-alkyltaurines such as the one prepared by reactingdodecylamine with sodium isethionate according to the teaching of U.S.Pat. No. 2,658,072, N-higher alkyl aspartic acids such as those producedaccording to the teaching of U.S. Pat. No. 2,438,091, and the productsdescribed in U.S. Pat. No. 2,528,378.

Cationic surfactants can also be used in the shampoo compositions,primarily as conditioning agents, but are generally less preferred.Cationic surfactant concentrations should generally not exceed about 5%by weight of the shampoo composition.

Suitable nonionic surfactants include those broadly defined as compoundsproduced by the condensation of alkylene oxide groups (hydrophilic innature) with an organic hydrophobic compound, which may be aliphatic oralkyl aromatic in nature. Preferred classes of nonionic surfactants foruse in the shampoo compositions include:

1) polyethylene oxide condensates of alkyl phenols, e.g., thecondensation products of alkyl phenols having an alkyl group containingfrom about 6 to about 20 carbon atoms in either a straight chain orbranched chain configuration, with ethylene oxide, the ethylene oxidebeing present in amounts equal to from about 10 to about 60 moles ofethylene oxide per mole of alkyl phenol;

2) nonionic surfactants derived from the condensation of ethylene oxidewith the product resulting from the reaction of propylene oxide andethylene diamine products;

3) condensation products of aliphatic alcohol's having from about 8 toabout 18 carbon atoms, in either straight chain or branched chainconfiguration, with ethylene oxide, e.g., a coconut alcohol ethyleneoxide condensate having from about 10 to about 30 moles of ethyleneoxide per mole of coconut alcohol, the coconut alcohol fraction havingfrom about 10 to about 14 carbon atoms;

4) long chain tertiary amine oxides corresponding to the followinggeneral formula:

 wherein R₁ contains an alkyl, alkenyl or monohydroxy alkyl radical offrom about 8 to about 18 carbon atoms, from 0 to about 10 ethylene oxidemoieties, and from 0 to about 1 glyceryl moiety, and R₂ and R₃ containfrom about I to about 3 carbon atoms and from 0 to about 1 hydroxygroup, e.g., methyl, ethyl, propyl, hydroxyethyl, or hydroxypropylradicals;

5) long chain tertiary phosphine oxides corresponding to the followinggeneral formula:

 wherein R contains an alkyl, alkenyl or monohydroxyalkyl radicalranging from about 8 to about 18 carbon atoms in chain length, from 0 toabout 10 ethylene oxide moieties and from 0 to about 1 glyceryl moietyand R′ and R″ are each alkyl or monohydroxyalkyl groups containing fromabout 1 to about 3 carbon atoms;

6) long chain dialkyl sulfoxides containing one short chain alkyl orhydroxy alkyl radical of from about 1 to about 3 carbon atoms (usuallymethyl) and one long hydrophobic chain which include alkyl, alkenyl,hydroxy alkyl, or keto alkyl radicals containing from about 8 to about20 carbon atoms, from 0 to about 10 ethylene oxide moieties and from 0to about 1 glyceryl moiety;

7) alkyl polysaccharide (APS) surfactants such as the alkylpolyglycosides, as described in U.S. Pat. No. 4,565,647, which have ahydrophobic group with about 6 to about 30 carbon atoms andpolysaccharide (e.g., polyglycoside) as the hydrophilic group, andoptionally have a polyalkylene-oxide group joining the hydrophobic andhydrophilic moieties, wherein the alkyl group (i.e., the hydrophobicmoiety) can be saturated or unsaturated, branched or unbranched, andunsubstituted or substituted (e.g., with hydroxy or cyclic rings); and

8) polyethylene glycol (PEG) glyceryl fatty esters, such as those of theformula R(O)OCH₂CH(OH)CH₂(OCH₂CH₂)_(n)OH wherein n is from about 5 toabout 200, preferably from about 20 to about 100, and R is an aliphatichydrocarbyl having from about 8 to about 20 carbon atoms.

Zwitterionic surfactants suitable for use in the shampoo compositionsherein can be broadly described as derivatives of aliphatic quaternaryammonium, phosphonium, and sulfonium compounds, in which the aliphaticradicals can be straight or branched chain, and wherein one of thealiphatic substituents contains from about 8 to about 18 carbon atomsand one contains an anionic group, e.g., carboxy, sulfonate, sulfate,phosphate, or phosphonate. Such suitable zwitterionic surfactants can berepresented by the formula:

wherein R² contains an alkyl, alkenyl, or hydroxy alkyl radical of fromabout 8 to about 18 carbon atoms, from 0 to about 10 ethylene oxidemoieties and from 0 to about 1 glyceryl moiety; Y is selected from thegroup consisting of nitrogen, phosphorus, and sulfur atoms; R³ is analkyl or monohydroxyalkyl group containing about 1 to about 3 carbonatoms; X is 1 when Y is a sulfur atom, and 2 when Y is a nitrogen orphosphorus atom; R⁴ is an alkylene or hydroxyalkylene of from about 1 toabout 4 carbon atoms and Z is a radical selected from the groupconsisting of carboxylate, sulfonate, sulfate, phosphonate, andphosphate groups.

Other zwitterionic surfactants such as betaines can also be used in theshampoo compositions, examples of which include the high alkyl betaines,such as coco dimethyl carboxymethyl betaine, cocoamidopropyl betaine,cocobetaine, lauryl amidopropyl betaine, oleyl betaine, lauryl dimethylcarboxymethyl betaine, lauryl dimethyl alpha-carboxyethyl betaine, cetyldimethyl carboxymethyl betaine, lauryl bis-(2-hydroxyethyl)carboxymethyl betaine, stearyl bis-(2-hydroxypropyl) carboxymethylbetaine, oleyl dimethyl gamma-carboxypropyl betaine, and laurylbis-(2-hydroxypropyl)alpha-carboxyethyl betaine. The sulfobetaines maybe represented by coco dimethyl sulfopropyl betaine, stearyl dimethylsulfopropyl betaine, lauryl dimethyl sulfoethyl betaine, laurylbis-(2-hydroxyethyl) sulfopropyl betaine and the like; amidobetaines andamidosulfobetaines, wherein the RCONH(CH₂)₃ radical is attached to thenitrogen atom of the betaine are also useful in this invention.

Cationic Polymer

The shampoo compositions of the present invention comprise a watersoluble cationic polymer at concentrations effective to enhancedeposition of the latex polymer particles described hereinafter. Suchconcentrations will typically be from about 0.01% to about 5%,preferably from about 0.05% to about 3%, more preferably from about 0.1%to about 2%, by weight of the shampoo compositions.

The weight ratio of cationic polymer to latex polymer (latex polymerdescribed hereinafter) in the shampoo compositions is from about 1:1 toabout 1:60, preferably from about 1:1 to about 1:30, more preferablyfrom about 1:1 to about 1:15, and the weight ratio of cationic polymerto organic oil (organic oil described hereinafter) is from 15:1 to about1:15, preferably from about 10:1 to about 1:10, and more preferably fromabout 5:1 to about 1:5.

Water soluble cationic polymers for use in the shampoo compositions arethose which are sufficiently soluble in water to form a substantiallyclear solution at a concentration of at least about 0.1% by weight ofthe cationic polymer in water (distilled or equivalent) at 25° C.,preferably at a concentration of at least about 0.5%, and morepreferably at a concentration of at least about 1.0%, by weight of thecationic polymer in water at 25° C.

Suitable cationic polymers, and their effective concentrations, arethose which are physically and chemically compatible with the essentialcomponents of the shampoo composition of the present invention, andwhich can enhance deposition of the latex polymer particles describedhereinafter. The average molecular weight of such suitable cationicpolymers will generally be at least about 5,000, preferably betweenabout 10,000 and about 10 million, more preferably between about 100,000and about 2 million.

Suitable cationic polymers will typically have cationicnitrogen-containing moieties such as quaternary ammonium or cationicamino moieties, or a mixture thereof. The precise cationic chargedensity is not believed to be critical to the invention. Any anioniccounterions can be utilized for the cationic polymers so long as thewater solubility criteria described hereinbefore is met. Suitablecounterions include halides (e.g., Cl, Br, I, or F, preferably Cl, Br,or I), sulfate, and methylsulfate. Others can also be used, as this listis not exclusive. Generally, it is preferred that cationic chargedensity be at least about 0.2 meq/gram, more preferably at least about0.4 meq/gram. Charge density of amino-containing polymers may varydepending upon pH and the isoelectric point of the amino groups. It ispreferred that the charge density be above about 0.2 meq/gram(preferably above 0.4 meq/gram) at the pH of intended use, which will ingeneral be from about pH 3 to about pH 9, most generally from about pH 4to about pH 8.

The cationic nitrogen-containing moiety will be present generally as asubstituent on a fraction of the total monomer units of the cationicpolymer. Thus, the cationic polymer can comprise copolymers,terpolymers, etc. of quaternary ammonium or cationic amine-substitutedmonomer units and other non-cationic units referred to herein as spacermonomer units. Such polymers are known in the art, and a variety can befound in the CTFA Cosmetic Ingredient Dictionary, 3rd edition, edited byEstrin, Crosley, and Haynes, (The Cosmetic, Toiletry, and FragranceAssociation, Inc., Washington, D.C., 1982).

Suitable cationic polymers for use in the shampoo composition include,for example, copolymers of vinyl monomers having cationic amine orquaternary ammonium functionalities with water soluble spacer monomerssuch as acrylamide, methacrylamide, alkyl and dialkyl acrylamides, alkyland dialkyl methacrylamides, alkyl acrylate, alkyl methacrylate, vinylcaprolactone, and vinyl pyrrolidone. The alkyl and dialkyl substitutedmonomers preferably have C₁-C₇ alkyl groups, more preferably C₁-C₃ alkylgroups. Other suitable spacer monomers include vinyl esters, vinylalcohol (made by hydrolysis of polyvinyl acetate), maleic anhydride,propylene glycol, and ethylene glycol.

The cationic amines can be primary, secondary, or tertiary amines,depending upon the particular species and the pH of the shampoocomposition. In general, secondary and tertiary amines, especiallytertiary amines, are preferred.

Amine-substituted vinyl monomers can be polymerized in the amine form,and then optionally can be converted to ammonium by a quaternizationreaction. Amines can also be similarly quaternized subsequent toformation of the polymer. For example, tertiary amine functionalitiescan be quaternized by reaction with a salt of the formula R′X wherein R′is a short chain alkyl, preferably a C₁-C₇ alkyl, more preferably aC₁-C₃ alkyl, and X is an anion which forms a water soluble salt with thequaternized ammonium.

Suitable cationic amino and quaternary ammonium monomers include, forexample, vinyl compounds substituted with dialkylaminoalkyl acrylate,dialkylaminoalkyl methacrylate, monoalkylaminoalkyl acrylate,monoalkylaminoalkyl methacrylate, trialkyl methacryloxyalkyl ammoniumsalt, trialkyl acryloxyalkyl ammonium salt, diallyl quaternary ammoniumsalts, and vinyl quaternary ammonium monomers having cyclic cationicnitrogen-containing rings such as pyridinium, imidazolium, andquaternized pyrrolidone, e.g., alkyl vinyl imidazolium, alkyl vinylpyridinium, alkyl vinyl pyrrolidone salts. The alkyl portions of thesemonomers are preferably lower alkyls such as the C₁-C₃ alkyls, morepreferably C₁ and C₂ alkyls. Suitable amine-substituted vinyl monomersfor use herein include dialkylaminoalkyl acrylate, dialkylaminoalkylmethacrylate, dialkylaminoalkyl acrylamide, and dialkylaminoalkylmethacrylamide, wherein the alkyl groups are preferably C₁-C₇hydrocarbyls, more preferably C₁-C₃, alkyls.

The cationic polymers for use in the shampoo compositions can comprisemixtures of monomer units derived from amine- and/or quaternaryammonium-substituted monomer and/or compatible spacer monomers.

Specific cationic polymers suitable for use in the shampoo compositionsinclude copolymers of 1-vinyl-2-pyrrolidone and1-vinyl-3-methylimidazolium salt (e.g., chloride salt) (referred to inthe industry by the Cosmetic, Toiletry, and Fragrance Association,“CTFA”, as Polyquaternium-16), such as those commercially available fromBASF Wyandotte Corp. (Parsippany, N.J., USA) under the LUVIQUATtradename (e.g., LUVIQUAT FC 370 and FC 905); copolymers of1-vinyl-2-pyrrolidone and dimethylaminoethyl methacrylate (referred toin the industry by CTFA as Polyquaternium-11) such as those commerciallyavailable from Gaf Corporation (Wayne, N.J., USA) under the GAFQUATtradename (e.g., GAFQUAT 755N); cationic diallyl quaternaryammonium-containing polymers, including, for example,dimethyldiallylammonium chloride homopolymer and copolymers ofacrylamide and dimethyldiallylammonium chloride, referred to in theindustry (CTFA) as Polyquaternium 6 and Polyquaternium 7, respectively,such materials being available from Merck and Co., Inc. in theirMerquatR series; copolymers of acrylamide and dimethyl diallyl ammoniumchloride, such as those available under the MERQUAT tradename fromCalgon Corp. (Pittsburgh, Pa., USA) (e.g., MERQUAT 550); and mineralacid salts of amino-alkyl esters of homo- and co-polymers of unsaturatedcarboxylic acids having from 3 to 5 carbon atoms, as described in U.S.Pat. No. 4,009,256.

Other suitable cationic polymers include polysaccharide polymers, suchas cationic cellulose derivatives and cationic starch derivatives. Thesepolysaccharide polymers can be represented by the formula:

wherein A is an anhydroglucose residual group, such as a starch orcellulose anhydroglucose residual; R is an alkylene oxyalkylene,polyoxyalkylene, or hydroxyalkylene group, or combination thereof; R¹,R², and R³ independently are alkyl, aryl, alkylaryl, arylalkyl,alkoxyalkyl, or alkoxyaryl groups, each group containing up to about 18carbon atoms, and the total number of carbon atoms for each cationicmoiety (i.e., the sum of carbon atoms in R¹, R² and R³) preferably beingabout 20 or less; and X is an anionic counterion, as previouslydescribed. The degree of cationic substitution in these polysaccharidepolymers is typically from about 0.01-1 cationic groups peranhydroglucose unit.

Cationic cellulose includes the polymeric quaternary ammonium salts ofhydroxyethyl cellulose reacted with lauryl dimethyl ammonium-substitutedopoxide, referred to in the industry (CTFA) as Polyquaternium 24. Thesematerials are available from Amerchol Corp. (Edison, N.J., USA) underthe tradename Polymer LM-200. Cationic cellulose is also available fromAmerchol Corp. (Edison, N.J., USA) in their Polymer JR and LR series ofpolymers, as salts of hydroxyethyl cellulose reacted with trimethylammonium substituted epoxide, referred to in the industry (CTFA) asPolyquaternium 10.

Other suitable cationic polymers include cationic guar gum derivatives,such as guar hydroxypropyltrimonium chloride, quaternarynitrogen-containing cellulose ethers and copolymers of etherifiedcellulose and starch.

Organic Oil

The shampoo compositions of the present invention comprise an organicoil in an amount effective to further enhance the deposition of thelatex polymer particles on hair in the presence of cationic polymer, andpreferably in an amount sufficiently low to avoid causing excessivelyconditioned or oily hair or lather tradeoffs.

The organic oil is present in the shampoo compositions at aconcentration generally ranging from about 0.05% to about 5%, preferablyfrom about 0.1% to about 3%, more preferably from about 0.1% to about1.5%, wherein the weight ratio of organic oil to latex polymer rangesfrom about 1:40 to about 2:1, more preferably from about 1:25 to about1:1, even more preferably from about 1:15 to about 1:2.

It was found that the organic oil, which is a known hair conditioningagent, also acts to enhance deposition of latex polymer particles onhair in the presence of cationic polymer. It was discovered that thelatex deposition profile for certain combinations of cationic polymerand organic oil were superior to the latex deposition profiles fromcomparable shampoo products containing only cationic polymer and shampooproducts containing only organic oil.

As used herein, “organic oils” means any water-insoluble hydrocarbonoil, water-insoluble fatty ester, or mixture thereof, which is also apourable liquid under ambient conditions. Suitable organic oils willgenerally have a viscosity under ambient conditions of less than about3×10⁶ cs, preferably less than about 2×10⁶ cs, more preferably less thanabout 1.5×10⁶ cs.

Suitable organic oils include hydrocarbon oils having at least about 10carbon atoms, such as cyclic hydrocarbons, straight chain aliphatichydrocarbons (saturated or unsaturated), and branched chain aliphatichydrocarbons (saturated or unsaturated), including polymers thereof.Straight chain hydrocarbon oils will preferably contain from about 12 toabout 19 carbon atoms. Branched chain hydrocarbon oils, includinghydrocarbon polymers, can and typically will contain higher numbers ofcarbon atoms. Specific examples include paraffin oil, mineral oil,saturated and unsaturated dodecane, saturated and unsaturated tridecane,saturated and unsaturated tetradecane, saturated and unsaturatedpentadecane, saturated and unsaturated hexadecane, polybutene,polydecene, and mixtures thereof. Branched-chain isomers of thesecompounds, as well as of higher chain length hydrocarbons, can also beused. Exemplary branched-chain isomers are highly branched saturated orunsaturated alkanes, such as the permethyl-substituted isomers, e.g.,the permethyl-substituted isomers of hexadecane and eicosane, such as 2,2, 4, 4, 6, 6, 8, 8-dimethyl-10-methylundecane and 2, 2, 4, 4, 6,6-dimethyl-8-methylnonane, sold by Permethyl Corporation. Preferred arehydrocarbon polymers such as polybutene and polydecene, especiallypolybutene.

Other suitable organic oils include fatty esters having at least 10carbon atoms, and include esters with hydrocarbyl chains derived fromfatty acids or alcohol's, e.g., mono-esters, polyhydric alcohol esters,and di- and tri-carboxylic acid esters. The hydrocarbyl radicals of thefatty esters hereof can also include or have covalently bonded theretoother compatible functionalities, such as amides and alkoxy moieties(e.g., ethoxy or ether linkages, etc.).

Fatty esters include monocarboxylic acid esters of alcohol's and/oracids of the formula R′COOR wherein alkyl or alkenyl radicals and thesum of carbon atoms in R′ and R is at least 10, preferably at least 20.

Other fatty esters suitable for use in the shampoo compositions includealkyl and alkenyl esters of fatty acids having aliphatic chains withfrom about 10 to about 22 carbon atoms, and alkyl and alkenyl fattyalcohol carboxylic acid esters having an alkyl and/or alkenylalcohol-derived aliphatic chain with about 10 to about 22 carbon atoms,and combinations thereof. Specific examples of such fatty esters includeisopropyl isostearate, hexyl laurate, isohexyl laurate, isohexylpalmitate, isopropyl palmitate., decyl oleate, isodecyl oleate,hexadecyl stearate, decyl stearate, isopropyl isostearate, dihexyldecyladipate, lauryl lactate, myristyl lactate, cetyl lactate, oleylstearate, oleyl oleate, oleyl myristate, lauryl acetate, cetylpropionate, and oleyl adipate.

Suitable monocarboxylic acid esters need not necessarily contain atleast one chain with at least 10 carbon atoms, so long as the totalnumber of aliphatic chain carbon atoms is at least 10. Specific examplesof such esters include diisopropyl adipate, diisohexyl adipate, anddiisopropyl sebacate.

Other suitable fatty esters includes di- and tri-alkyl and alkenylesters of carboxylic acids, examples of which include esters of C₄-C₈dicarboxylic acids such as C₁-C₂₂ esters (preferably C₁-C₆) of succinicacid, glutaric acid, adipic acid, hexanoic acid, heptanoic acid, andoctanoic acid. Specific examples include isocetyl stearyol stearate,diisopropyl adipate, and tristearyl citrate.

Polyhydric alcohol esters may also be used as the organic oil in theshampoo compositions, examples of which include alkylene glycol esters,for example ethylene glycol mono and di-fatty acid esters, diethyleneglycol mono- and di-fatty acid esters, polyethylene glycol mono- anddi-fatty acid esters, propylene glycol mono- and di-fatty acid esters,polypropylene glycol monooleate, polypropylene glycol 2000 monostearate,ethoxylated propylene glycol monostearate, glyceryl mono- and di-fattyacid esters, polyglycerol poly-fatty acid esters, ethoxylated glycerylmonostearate, 1,3-butylene glycol monostearate, 1,3-butylene glycoldistearate, polyoxyethylene polyol fatty acid ester, sorbitan fatty acidesters, and polyoxyethylene sorbitan fatty acid esters.

Glycerides may also be used as the organic oil in the shampoocompositions, examples of which include mono-, di-, and tri-esters ofglycerol and long chain carboxylic acids, such as C₁₀-C₂₂ carboxylicacids. A variety of these types of materials can be obtained fromvegetable and animal fats and oils, such as castor oil, safflower oil,cottonseed oil, corn oil, olive oil, cod liver oil, almond oil, avocadooil, palm oil, sesame oil, lanolin and soybean oil. Synthetic oilsinclude triolein and tristearin glyceryl dilaurate. Preferred glyceridesare di-, and tri-glycerides. Especially preferred are triglycerides.

Aqueous Carrier

The shampoo compositions of the present invention are typically in theform of pourable liquids (under ambient conditions). The shampoocompositions will therefore typically comprise an aqueous carrier, whichis present at a level of from about 20% to about 95%, preferably fromabout 60% to about 85%, by weight of the shampoo compositions. Theaqueous carrier may comprise water, or a miscible mixture of water andorganic solvent, but preferably comprises water with minimal or nosignificant concentrations of organic solvent, except as otherwiseincidentally incorporated into the composition as minor ingredients ofother essential or optional components.

Latex Polymer Particles

The shampoo compositions of the present invention comprise latex polymersystems containing water insoluble, latex polymer particles dispersed ina continuous aqueous phase. These compositions comprise up to about 25%,preferably from about 0.05% to about 25%, more preferably from 0.05% toabout 15%, more preferably from about 0.1% to about 10%, and mostpreferably from about 0.5% to about 7%, by weight, of the latex polymerparticles.

The latex polymer systems for use in the shampoo compositions aredispersions, preferably colloidal dispersions, of water insolublepolymer particles in a continuous aqueous medium. Once incorporated intothe shampoo compositions, the latex polymer particles may be maintainedas dispersed particles primarily by surfactant, and to some extent (inthe case of colloidal dispersions) by the inherent dispersioncharacteristics of colloidal particles in such compositions. Thedispersed particles will generally have an average diameter of less thanabout 4 μm, preferably from about 0.005 to about 1 μm, more preferablyfrom about 0.05 to about 0.5 μm.

Latex polymer particles for use in the shampoo compositions may benonionic, anionic, cationic, zwitterionic or amphoteric. Latex polymerparticles are well known in the polymer art, and for purposes of thepresent invention, may be obtained, prepared or synthesized by any meansprovided that the resulting latex polymer particles have the requisitecharacteristics as described herein, and provided that such polymers arecompatible with the essential components of the shampoo compositions, ordo not otherwise unduly impair cleaning and/or styling performance ofthe composition.

Monomers suitable for use in the polymerization or copolymerizationmethods described briefly herein, include, styrene, butadiene, ethylene,acrylonitrile, chloroprene, vinylidene chloride, isoprene, isobutyleneand vinyl chloride, and esters of acrylic, methacrylic, vinylacetic,maleic, crotonic and itaconic acids. These monomers may be used alone orin combination, or they may be mixed with one or more ionic monomers,e.g., acrylic acid, methacrylic acid, to form charged latex polymersystems. Many other monomers are known for use in making latex polymers,and can be used for purposes of preparing the latex polymers herein.

Specific latex polymers for use in the composition include, but are notlimited to, the following latex polymer systems grouped according tomanufacturer (mfr) or distributor.

Mfr. or Distributor Tradename Latex Polymer Dow 246NA, DL225NAstyrene/butadiene/ acrylic acid Goodrich Hycar 1562 Carboxybutadiene/acrylonitrile Goodyear Chemigum Latex 6271 Styrene/Acrylic Ester HoechstAppretan ANT Acrylic Appretan MB Vinyl Acetate/Ethylene Appretan EMVinyl Acetate/Ethylene Appretan TV Vinyl Acetate/Ethylene AppretanV-3749 Interpolymer Syntran 1026 Acrylic Acid/Ethylene/ Styrene SyntranEX26-2,-5,-7, Methylmethacrylate/ -9,-13,-20 butylacrylate NationalAdhesives National 125 4477 Acrylic & Resins National 125 4445 AcrylicNational 125 2833 Vinyl Acetate/Acrylic National 125 2869 VinylAcetate/Acrylic National 125 2873 Vinyl Acetate/Acrylic PCUK ColaperleSPA Acrylic Protex Acrymul AM 176 R Acrylic (Reactive) Rhone PoulencRhodopas A-012-P Vinyl Acetate Rhodopas A-013-P Vinyl Acetate RhodapasSD-215 Acrylic Acid Rhodopas SB-02 Styrene/Butadiene Rhodopas ST-246Styrene/Butadiene Rhodopas SB-153 Styrene/Butadiene Rhodopas GB-012Styrene/Butadiene Rohm and Haas Primal B52 Acrylic Primal K3 AcrylicPrimal TR 485 Acrylic Primal AS 95 Acrylic Primal AC 33 Acrylic AcidPrimal TR-93 Acrylic Acid Primal HA-8 Acrylic Acid Primal E-358 AcrylicAcid Williams Lucidene 347 Styrene/Acrylic Acid Witco Witcobond 160Polyurethane

Optional Ingredients

The shampoo compositions of the present invention may comprise one ormore optional materials to improve or modify aesthetics, stability,usage benefits, or other benefits or characteristics commonly associatedwith the use of such optional materials. These optional materials shouldbe physically and chemically compatible with the essential components ofthe shampoo compositions, or should not otherwise unduly impair cleaningand/or styling performance.

Optional materials include, but are not limited to, pearlescent aids,such as coated mica, ethylene glycol distearate; anti-dandruff actives;opacifiers, such as TiO₂; preservatives, such as benzyl alcohol,1,3-bis(hydroxymethyl)-5,5-dimethyl-2,3-imidazolidinedione (e.g.,Glydant, Glyco, Inc., Greenwich, Conn., USA),methylchloroisothiazolinone (e.g., Kathon, Rohm & Haas Co.,Philadelphia, Pa., USA), methyl paraben, propyl paraben, andimidazolidinyl urea; fatty alcohol's, such as cetearyl alcohol, cetylalcohol, and stearyl alcohol; sodium chloride; ammonium chloride; sodiumsulfate; ethyl alcohol; pH adjusting aids, such as citric acid, sodiumcitrate, succinic acid, phosphoric acid, monosodium phosphate, disodiumphosphate, sodium hydroxide, and sodium carbonate; coloring agents ordyes; perfumes; sequestering agents, such as disodium ethylenediaminetetra-acetate, and latex depostions aids.

Anti-static agents may also be used to the extent that it does notunduly interfere with the surfactant or other charged component of theshampoo compositions. Suitable anti-static agents include tricetylmethyl ammonium chloride. The shampoo compositions may contain fromabout 0.1% to about 5% of the anti-static agent, Other optionalmaterials include thickeners, lather boosters and viscosity modifiers,examples of which include ethanolamide of a long chain fatty acid (e.g.,polyethylene (3) glycol lauramide and coconut monoethanolamide) andammonium xylene sulfonate.

These optional materials, individually or in combination, may be used inthe shampoo compositions at concentrations of from about 0.01% to about10%, preferably from about 0.05% to about 5.0%, by weight of the shampoocompositions.

Method of Manufacture

The shampoo compositions of the present invention can be prepared byusing various formulation and mixing techniques or methods known in theart for preparing surfactant or latex-containing compositions, or othersimilar compositions.

In accordance with one such conventional method, surfactant solutionsare mixed at about 72° C. in an isolated vessel. The organic oil and anysolid materials are added to the heated surfactant mixture. Theresulting mixture is heated and agitated to allow melting of the solidmaterials. Preservatives are then added before pumping the mixturethrough a high shear mill, and then through a heat exchanger to cool themixture to ambient temperature. In a second isolated vessel, thecationic polymer is dispersed and hydrated in water, and then added tothe cooled mixture described hereinabove. The latex polymer particles,and optional perfumes, are then added to the mixture. Other optional orminor ingredients are added to the mixture to achieve the desiredcomposition and concentration.

Method of Use

The shampoo compositions of the present invention are utilizedconventionally, i.e., the hair is shampooed by applying an effectiveamount of the shampoo composition to the scalp, and then rinsing it outwith water. Application of the shampoo to the scalp in general,encompasses massaging or working the shampoo in the hair such that allor most of the hair on the scalp is contacted. The term an “effectiveamount” as used herein, is an amount which is effective in cleaning andconditioning the hair. Generally, from about 1 g to about 20 g of theshampoo composition is applied for cleaning and conditioning the hair.Preferably, the shampoo compositions are applied to hair in a wet ordamp state.

The shampoo compositions of the present invention are also useful forcleaning skin, or in other applications where cleaning and latex polymerdeposition would be useful. For such applications, the compositions areapplied to the skin or other surface in a conventional manner, such asby rubbing or massaging the skin or other surface with the composition,optionally in the presence of water, and then rinsing it away withwater.

EXAMPLES

The following Examples I-XIII illustrate specific embodiments of theshampoo compositions of the present invention, but are not intended tobe limiting thereof. Other modifications can be undertaken by theskilled artisan without departing from the spirit and scope of thisinvention.

All examples are prepared by conventional formulation and mixingtechniques. Component amounts are listed as weight percents and excludeminor materials such as diluents, filler, etc. The listed formulationstherefore comprise the listed components and any minor materialsassociated with such components.

EXAMPLES I-V

Component I II III IV V Ammonium laureth(3) sulfate 10.0 10.0 9.7 9.78.0 Ammonium lauryl sulfate 3.5 2.0 Cocamidopropyl betaine 5.0 4.3 2.0Sodium lauryl sarcosinate 3.3 Coconut monoethanol amide 1.0 0.7 0.5Ethylene glycol distearate 2.0 2.0 2.0 Cetyl alcohol 0.4 0.4 0.4 Stearylalcohol 0.2 0.2 0.2 Rhoplex NW-2744¹ 6.0 AQ 29D² 3.0 DL 225NA³ 1.5Syntran EX26-13⁴ 4.0 BAF691A⁵ 7.0 Gafquat 755⁶ 0.7 UCare Polymer LR30M⁷1.0 UCare Polymer JR30M⁸ 0.5 Luviquat FC 905⁹ 1.0 N-Hance 3196¹⁰ 0.3Isocetyl stearyol stearate 1.0 Permethyl 102A¹¹ 1.0 Light mineral oil0.25 Palm oil 1.0 Indopol L-14¹² 0.5 Perfume 1.0 1.0 1.0 1.0 1.0Preservative 0.3 0.3 0.3 0.3 0.3 Water qs qs qs qs qs ¹AcrylateCopolymer available from Rohm & Haas ²Aqueous dispersion ofDiglycol/Cyclohexanedimethanol/Isophthalates/SulfoisophthalatesCopolymer available from Eastman ³Emulsion of styrene/butadiene polymeravailable from Dow Chemicals ⁴Acrylic Latex, aqueous dispersion ofmethyl methacrylate/butyl acrylate/ammonium methacrylate/allylmethacrylate copolymer available from Interpolymer ⁵Acrylic latexpolymer available from Rohm and Haas ⁶Polyquaterium-11 available fromGaf Corp. ⁷Polyquaternium-10 available from Amerchol Corp.⁸Polyquaternium-10 available from Amerchol Corp. ⁹Tradename of BASFWyandotte Corporation for copolymer of vinyl pyrrolidone and methylvinyl imidazolium chloride (95:5 weight ratio) ¹⁰Tradename for GuarHydroxypropyltrimonium Chloride, a cationic polymer available fromAqualon ¹¹Permethyl-substituted isomer of eicosane available fromPermethyl Corp. ¹²Low molecular weight polybutene available from AmocoChemicals

EXAMPLES VI-X

Component VI VII VIII IX X Ammonium laureth(3) sulfate 9.7 9.7 4.0 10.05.0 Alkyl glycerol sulfonate 8.0 5.0 Cocamidopropyl betaine 4.3 3.0 3.0Diammonium lauryl 4.3 2.0 2.0 sulfosuccinate Coconut monoethanol amide0.7 0.7 0.7 0.7 Ethylene glycol distearate 2.0 2.0 1.0 2.0 Cetyl alcohol0.4 0.4 0.4 Stearyl alcohol 0.2 0.2 0.2 Syntran 5170¹³ 6.0 RhodopasA-012-P¹⁴ 2.0 460NA¹⁵ 4.0 Syntran EX26-20¹⁶ 3.0 Witcobond 160¹⁷ 2.5MERQUAT 550¹⁸ 0.2 UCare polymer LR30M¹⁹ 0.3 UCare polymer JR30M²⁰ 0.4Polymer LM-200²¹ 0.1 Jaguar C-14S²² 0.35 Isocetyl stearyol stearate 1.0Permethyl 102A²³ 0.5 Light mineral oil 0.5 0.35 Indopol L-14²⁴ 0.25Perfume 1.0 1.0 1.0 1.0 1.0 Preservative 0.3 0.3 0.3 0.3 0.3 Water qs qsqs qs qs ¹³Acrylic Latex, aqueous dispersion of methylmethacrylate/butyl acrylate/ammonium methacrylate copolymer availablefrom Interpolymer ¹⁴Emulsion of vinyl acetate homopolymer available fromRhone Poulenc ¹⁵Emulsion of styrene/butadiene polymer available from DowChemicals ¹⁶Acrylic Latex, aqueous dispersion of methylmethacrylate/butyl acrylate/allyl methacrylate copolymer available fromInterpolymer ¹⁷Polyurethane latex polymer available from Witco¹⁸Copolymer of acrylamide and dimethyl diallyl ammonium chloride,available from Calgon Corp. ¹⁹Polyquaternium-10 available from AmercholCorp. ²⁰Polyquaternium-10 available from Amerchol Corp.²¹Polyquaternium-24 available from Amerchol Corp. ²²Tradename for GuarHydroxypropyltrimonium Chloride, a cationic polymer available from RhonePoulenc ²³Permethyl-substituted isomer of eicosane available fromPermethyl Corp. ²⁴Low molecular weight polybutene available from AmocoChemicals

EXAMPLES XI-XIII

Component Control XI XII XIII Ammonium laureth(3) sulfate 7.7 7.7 9.79.7 Cocamidopropyl betaine 3.8 3.8 4.3 4.3 Coconut monoethanol amide — —0.7 0.7 Lauryl N-methyl glucamide 2.5 2.5 — — Ethylene glycol distearate2.0 2.0 2.0 2.0 Cetyl alcohol 0.4 0.4 0.4 0.4 Stearyl alcohol 0.2 0.20.2 0.2 Syntran EX26-9²⁵ 4.0 4.0 — — Syntran EX26-13²⁶ — — 3.0 3.0 UCarepolymer JR30M²⁷ 0.3 0.3 0.3 0.3 Indopol L-14²⁸ — 0.5  0.25 0.5 Perfume1.0 1.0 1.0 1.0 Preservative 0.3 0.3 0.3 0.3 Water qs qs qs qs StylingControl Visual (0-5) 3.2 4.2 3.9 4.3 Stiffness (0-8)  4.4″  7.0″  5.4″ 8.0″ Latex deposition Low High Medium High ²⁵Acrylic Latex, aqueousdispersion of methyl methacrylate/butyl acrylate/ammonium methacrylateavailable from Interpolymer ²⁶Acrylic Latex, aqueous dispersion ofmethyl methacrylate/butyl acrylate/ammonium methacrylate/allylmethacrylate copolymer available from Interpolymer ²⁷Polyquaternium-10available from Amerchol Corp. ²⁸Low molecular weight polybuteneavailable from Amoco Chemicals

The shampoo compositions illustrated in Examples XI-XIII, including thecontrol formulation also illustrated hereinabove, are evaluated forstyling performance and latex deposition in accordance with thefollowing test methods.

Test Method: Styling Performance

An 8″ human hair switch is shampooed by applying an effective amount ofthe shampoo composition and then rinsing it out with water. Excess wateris removed from the rinsed hair by squeezing the hair between the thumband forefinger, moving the hand down the length of the hair switch. Thehair is then allowed to dry overnight (about 8-12 hours). The dried hairis then evaluated for styling performance in accordance with thefollowing two methods.

In the first test method, the dried hair is visually inspected and givena subjective score of from 0 to 5, wherein a score of 0 represents full,fluffy, unstyled hair and a score of 5 represents a stiff rod ofexcessively styled hair. Intermediate scores represent intermediatelevels of styling control.

In the second test method, the styling performance (stiffness) of thedried hair is measured by moving the dried hair switch along an inclinedplane to determine the maximum length of the switch that can be movedout over the end of the plane until the weight of the switch pulls itdown below the level of the plane and overcomes the ability of the hairswitch to defy gravity. The maximum movement length will vary from 0inches (unstyled hair) to 8 inches (stiff rod of excessively styledhair).

Test Method: Latex Deposition

Each dried hair switch is visually inspected by scanning electronmicroscopy (SEM). Under SEM, the extent of latex deposition on eachdried hair switch is subjectively evaluated relative to the latexdeposition on each of the other dried hair switches. The relative extentof latex deposition is identified as low, medium or high.

Test Results

It can be seen from the above-described test results that the stylingshampoo compositions illustrated in Examples XI-XIII, all of which arespecific embodiments of the present invention, exhibit improved stylingperformance and latex deposition.

What is claimed is:
 1. Shampoo compositions comprising: (A) from about0.5% to about 50% by weight of synthetic surfactant; (B) from about0.05% to about 25% by weight of dispersed latex polymer particles; (C)from about 0.01% to about 5% by weight of water-soluble cationicpolymer; (D) from about 0.05% to about 5% by weight of an organic oilwhich is selected from the group consisting of fatty ester havingaliphatic chains with a total of at least 10 carbon atoms and mixturesof fatty ester having aliphatic chains with a total of at least 10carbon atoms and water insoluble hydrocarbon oil having at least 10carbon atoms; (E) water, wherein the weight ratio of said cationicpolymer to said organic oil is from about 15:1 to about 1:5.
 2. Theshampoo compositions of claim 1 wherein the weight ratio of organic oilto latex polymer is from about 1:40 to about 2:1, the weight ratio ofcationic polymer to latex polymer is from about 1:1 to about 1:60, andthe weight ratio of the cationic polymer to organic oil is from about15:1 to about 1:15.
 3. The shampoo compositions of claim 2 wherein theweight ratio of organic oil to latex polymer is from about 1:15 to about1:2, the weight ratio of cationic polymer to latex polymer is from about1:1 to about 1:15, and the weight ratio of the cationic polymer toorganic oil is from about 10:1 to about 1:10.
 4. The shampoocompositions of claim 1 where said compositions comprise from about 0.1%to about 3% by weight of the organic oil.
 5. The shampoo compositions ofclaim 4 wherein said compositions comprise from about 0.1% to about 1.5%by weight of the organic oil.
 6. The shampoo compositions of claim 1wherein the hydrocarbon oil are straight chain hydrocarbons having fromabout 12 to about 19 carbon atoms, branched chain hydrocarbons having atleast about 12 carbon atoms, hydrocarbon polymers, or mixtures thereof.7. The shampoo compositions of claim 6 wherein the hydrocarbon oil ispolybutene.
 8. The shampoo compositions of claim 2 wherein the syntheticsurfactant is anionic surfactant, nonionic surfactant or mixturesthereof.
 9. The shampoo compositions of claim 8 wherein said compositioncomprises from about 5% to about 25% by weight of the syntheticsurfactant.
 10. The shampoo compositions of claim 2 wherein the latexpolymer particles are water-insoluble polymers having an averageparticle diameter of less than about 4 μm, and are selected from thegroup consisting of nonionic polymers, anionic polymers, cationicpolymers, zwitterionic polymers, amphoteric polymers, and mixturesthereof.
 11. The shampoo compositions of claim 10 wherein the latexpolymer particles have an average particle diameter of from about 0.005μm to about 1 μm.
 12. The shampoo compositions of claim 10 wherein saidcompositions comprise from about 0.05% to about 15%, by weight, of thelatex polymer particles.
 13. The shampoo compositions of claim 12wherein said compositions comprise from about 0.5% to about 7%, byweight, of the latex polymer particles.
 14. The shampoo compositions ofclaim 2 wherein said compositions comprise from about 0.1% to about 2%,by weight, of the water soluble cationic polymer.
 15. The shampoocomposition of claim 2 wherein said composition comprises from about 60%to about 85%, by weight, of water.
 16. A method of shampooing hair,which method comprises applying to hair from about 1 g to about 20 g ofthe shampoo composition of claim 1, and then rinsing the hair withwater.
 17. A method of shampooing hair, which method comprises applyingto hair from about 1 g to about 20 g of the shampoo composition of claim2, and then rinsing the hair with water.